|
|
UDP-glucose + monodeglucosyl_des-acyl_avenacin_A <=> des-acyl_avenacin_A + UDP + H+
|
2.4.1
|
–
|
|
MetaCyc:
RXN-15391
|
|
|
|
(3S)-2,3-epoxy-2,3-dihydrosqualene <=> beta-amyrin
|
5.4.99.34
germanicol synthase
5.4.99.39
beta-amyrin synthase
5.4.99.41
lupeol synthase
5.4.99.B2
|
–
–
–
–
|
|
BRENDA:
BR48944
KEGG:
R06469
MetaCyc:
RXN-7570
|
|
|
|
beta-amyrin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> maniladiol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.63
beta-amyrin 16beta-monooxygenase
|
–
|
|
MetaCyc:
RXN-15385
|
|
|
|
beta-amyrin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 12,13beta-epoxy-beta-amyrin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
|
MetaCyc:
RXN-15383
|
|
|
|
12,13beta-epoxy-16beta-hydroxy-beta-amyrin <=> monodeglucosyl_des-acyl_avenacin_A
|
not assigned
|
–
|
|
MetaCyc:
RXN-15392
|
|
|
|
maniladiol + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 12,13beta-epoxy-16beta-hydroxy-beta-amyrin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
|
MetaCyc:
RXN-15386
|
|
|
|
des-acyl_avenacin_A + N-methylanthraniloyl-beta-D-glucopyranose <=> avenacin_A-1 + D-glucose
|
2.3.1
|
–
|
|
MetaCyc:
RXN-15388
|
|
|
|
12,13beta-epoxy-beta-amyrin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 12,13beta-epoxy-16beta-hydroxy-beta-amyrin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
|
MetaCyc:
RXN-15384
|
|